Sodium‑chromium covariation in residual clinopyroxenes from abyssal peridotites sampled in the 43°–46°E region of the Southwest Indian Ridge

Mantle-derived peridotites sampled at three dredge sites between the Discovery and Indomed fracture zones on the Southwest Indian Ridge axis are analyzed for petrography and major and trace element mineral compositions. While textures and microstructures are those typical of normal residual peridotites these rocks display a large compositional variation encompassing the whole spectrum of abyssal peridotites even at the scale of a single dredge site (≤1km). Particularly, clinopyroxenes in peridotites dredged at 44.03°E show a huge variation in sodium contents positively correlated with chromium concentrations. Observed NaCr enrichments exceed the commonly reported contents of the spinel abyssal peridotites. Similar values are also found in very few peridotite samples collected at ultra-slow spreading ridges. Major substitutions governing the compositions of these clinopyroxenes suggest that NaCr covariation is caused by a more rapid decrease in Al-Tschermak's molecule with respect to the sodic components jadeite±kosmochlor, as Cr/Al increases and modal clinopyroxene decreases. We conclude that sodium and chromium enrichments must have occurred contemporaneously with aluminum depletion, i.e., during partial melting. Our modelling suggests that partial, non-modal, melting of a depleted peridotite in association with addition of sodium, by percolation of a Na-rich melt in the upwelling mantle, or Na diffusion from a nearby alkaline melt, may explain this enigmatic and counterintuitive trend.