Charge Transport and Degradation in HfO2 and HfOx Dielectrics

We combine experiments and simulations to investigate leakage current and breakdown (BD) in stoichiometric and sub-stoichiometric hafnium oxides. Using charge-transport simulations based on phonon-assisted carrier tunneling between trap sites, we demonstrate that higher currents generally observed in HfOx are due to a higher density of the as-grown oxygen vacancy defects assisting the charge transport. Reduction of the dielectric breakdown field (EBD) in HfOx is explained by the lower zero-field activation energy (EA,G) of the defect generation process, as extracted from time-dependent dielectric breakdown experiments.