Deprotonated amide nitrogen coordinating to the palladium(II) ion.Crystal and molecular structure of disodium bis)N-tosylglycinato-N,O)palladate(II)
Articolo
Data di Pubblicazione:
1990
Citazione:
Deprotonated amide nitrogen coordinating to the palladium(II) ion.Crystal and molecular structure of disodium bis)N-tosylglycinato-N,O)palladate(II) / Menabue, Ledi; Saladini, Monica; Sola, Marco. - In: INORGANIC CHEMISTRY. - ISSN 0020-1669. - STAMPA. - 29:(1990), pp. 1293-1295. [10.1021/ic00331a034]
Abstract:
The crystal and molecular structure of Disodium bis(N-toluensulfonylglycinateN,O) palladate(II) compexes is determined. The structure consists of monomeric bis(N-toluensulfonylglycinateN,O) palladate(II) dianion and sodium cations. The coordination geometry around Pd(II) ions is planar and the aminoacidate moiety acts as bidentate chelate ligand by means of deprotonated sulfonyl nitrogen and one carboxylate oxygen.
Tipologia CRIS:
Articolo su rivista
Keywords:
Palladium(II) complexes crystal structure; N-sulfonyl aminoacids metal complexes; sulfonyl nitrogen deprotonation
Elenco autori:
Menabue, Ledi; Saladini, Monica; Sola, Marco
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