Metal work function changes induced by organic adsorbates: A combined experimental and theoretical study

The role of molecular dipole moment, charge transfer, and Pauli repulsion in determining the workfunctionchange (DeltaPhi) at organic-metal interfaces has been elucidated by a combined experimental andtheoretical study of (CH3S)2/Au(111) and CH3S/Au(111). Comparison between experiment and theoryallows us to determine the origin of the interface dipole layer for both phases. For CH3S/Au(111), Delta Phican be ascribed almost entirely to the dipole moment of the CH3S layer. For (CH3S)2/Au(111), a Paulirepulsion mechanism occurs. The implications of these results on the interpretation of Delta Phi in the presenceof strongly and weakly adsorbed molecules is discussed.