Poly[3-hexyl-4-(6-bromohexyl)thiophene]: A key-intermediate for the synthesis of self-plastifying multifunctional polythiophenes

The synthesis and chemical polymerization of a thiophene disubstituted with an alkylic and an u-bromine functionalized oligomethylenicchain is described. The obtained polymer, namely the poly[3-hexyl-4-(6-bromohexyl)thiophene], is completely soluble in common organicsolvents and its structural, thermal and chemical–physical properties are compared with those of a ‘conventional’ bromohexyl 3-substitutedpolythiophene. The new polymer may be considered as a key-intermediate for the synthesis of multifunctional soluble polythiophenes sinceits self-plastifying feature may permit the insertion on the polymeric side-chains, by simple post-polymerization functionalization reactions,of sterically demanding or strongly interacting functional groups, without final solubility being compromised.q 2004 Elsevier Ltd. All rights reserved.