Hydrogen bonding and size effects of the cations on the coordination geometry of the metal ions. Tetrahalocobaltates(II) of the N-ethyl-, 2-ethyl- and 4-benzyl-piperidine cations. Crystal and molecular structure of the bis(4-benzylpiperidinium) tetrachlorocobaltate(II).
Articolo
Data di Pubblicazione:
1979
Citazione:
Hydrogen bonding and size effects of the cations on the coordination geometry of the metal ions. Tetrahalocobaltates(II) of the N-ethyl-, 2-ethyl- and 4-benzyl-piperidine cations. Crystal and molecular structure of the bis(4-benzylpiperidinium) tetrachlorocobaltate(II) / Antolini, Luciano; Marcotrigiano, Giuseppe Onofrio; Menabue, Ledi; Pellacani, Gian Carlo. - In: INORGANIC CHEMISTRY. - ISSN 0020-1669. - STAMPA. - 18:(1979), pp. 2652-2658. [10.1021/ic50200a003]
Abstract:
Some compounds of formula (LH)2(CoX4), where LH= N-ethyl-, 2-ethyl- and 4-benzylpiperidinium cation were synthesized and characterized by means of spectroscopic (UV-vis and vibratiional spectra), and magnetic measurements. For the chlorocobaltate complex with 4-benzylpiperidinium the crystal structure was determined. The far-IR spectra were discussed on the basis of C2 symmetry
Tipologia CRIS:
Articolo su rivista
Keywords:
tetrahalocobaltate crystal structure; tetrahalocobaltate coordination geometry; cobalt(II) complexes electronic spectra
Elenco autori:
Antolini, Luciano; Marcotrigiano, Giuseppe Onofrio; Menabue, Ledi; Pellacani, Gian Carlo
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